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Nice, Bob. Good get (for the wife!). It looks like something round may have sat on that portion of the brim, discoloring it. If a little distilled water doesn't clear it up, try white vinegar on it - maybe scrub a bit with a soft toothbrush. Of course, if either of those leave a watermark, you may have to give it a short dip in naphtha.
Distilled water > white vinegar > naphtha bath
Distilled water > white vinegar > naphtha bath


