I've used paint stripper and a pin to move it around. Try a tiny spot first. If it's a huge mess I wouldn't bother but small dots may be worth the trouble.
If it's latex paint you might be able to get it off with soap and water and a lot of hard scrubbing. On the other hand, overalls are supposed to have paint and grease and dirt on them.
I'll be following this thread with interest. I've had some luck getting latex out with solvents (diosol, Stripeeze, if that's still around. I have a half gallon from the '90's) but it's hit or miss on how badly these discolor the fabric.
Oil based paint seems like a mission impossible.
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